FRACTAL PHYSICS OF BRANCHED POLYMERS SYNTHESIS. POLYHYDROXYETHER

被引:0
作者
Kozlov, G. V. [1 ]
Beeva, D. A. [1 ]
Zaikov, G. E. [2 ]
Mlkitaev, A. K. [1 ]
机构
[1] Kabardino Balkar State Univ, Nalchik 360004, Russia
[2] Russian Acad Sci, NM Emanuel Inst Biochem Phys, Moscow 119334, Russia
来源
JOURNAL OF THE BALKAN TRIBOLOGICAL ASSOCIATION | 2013年 / 19卷 / 04期
关键词
branched polymer; polyhydroxyether; synthesis; conversion degree; reactionary medium; macromolecular coil; structure; fractal analysis; REACTION-KINETICS; GLASS-TRANSITION; RANDOM-WALKS; DIFFUSION; GELATION; STATES; NANOCOMPOSITES; DIMENSION; DYNAMICS; BEHAVIOR;
D O I
暂无
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
The questions of fractal analysis and irreversible aggregation models application for the description of branched polymers synthesis on the example of polyhydroxyether were considered. It has been shown that the indicated methods give correct quantitative description of the main characteristics of this class polymers: conversion degree, molecular weight and branching degree of polymer chain. The macromolecular coil structure, characterised by its fractal dimension, is the main factor defining the mentioned characteristics.
引用
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页码:615 / 642
页数:28
相关论文
共 78 条
[2]  
ALEKSANDROV IV, 1987, KHIM FIZ, V6, P1243
[3]  
ALEXANDER S, 1982, J PHYS LETT-PARIS, V43, pL625, DOI 10.1051/jphyslet:019820043017062500
[4]  
ALEXANDROWICH Z., 1986, FRACTALS PHYS, P172
[5]   KINETICS OF FORMATION AND MEAN SHAPE OF BRANCHED POLYMERS [J].
ALEXANDROWICZ, Z .
PHYSICAL REVIEW LETTERS, 1985, 54 (13) :1420-1423
[6]  
ASKADSKII A. A., 1968, PHYS CHEM POLARYLATE
[7]  
BARANOV VG, 1986, DOKL AKAD NAUK SSSR+, V290, P369
[8]  
Barnes FS, 1996, BIOFIZIKA+, V41, P790
[9]  
BEEVA D. A., 2006, MOL HIGH MOL CHEM TH, P49
[10]  
BELYI AA, 1986, DOKL AKAD NAUK SSSR+, V288, P151