Phosphine-Catalyzed [3+2] Cycloaddition Reactions of Azomethine Imines with Electron-Deficient Alkenes: A Facile Access to Dinitrogen-Fused Heterocycles

被引：55

作者：

Li, Zhen ^{[1
]}

Yu, Hao ^{[1
]}

Liu, Honglei ^{[1
]}

Zhang, Lei ^{[1
]}

Jiang, Hui ^{[1
]}

Wang, Bo ^{[1
]}

Guo, Hongchao ^{[1
]}

机构：

[1] China Agr Univ, Dept Appl Chem, Beijing 100193, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 06期

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

alkenes; azomethine imine; catalysis; cycloaddition reactions; phosphine; ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION; ALLENES; ANNULATIONS; ALLENOATES; ALKYNES;

D O I：

10.1002/chem.201303625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient method for the phosphine-catalyzed [3+2] cycloaddition reaction of azomethine imines with diphenylsulfonyl alkenes to give dinitrogen-fused bi- or tricyclic heterocyclic compounds in high yields has been described. Moreover, two phenylsulfonyl groups installed on the heterocyclic products could be conveniently removed or transformed to other functional groups, making the reaction more useful.

引用

页码：1731 / 1736

页数：6

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