Taco Complex Templated Syntheses of a Cryptand/Paraquat [2]Rotaxane and a [2]Catenane by Olefin Metathesis

被引：106

作者：

Li, Shijun ^{[1
,2
]}

Liu, Ming ^{[1
]}

Zheng, Bo ^{[1
]}

Zhu, Kelong ^{[1
]}

Wang, Feng ^{[1
]}

Li, Ning ^{[1
]}

Zhao, Xiao-Li ^{[3
]}

Huang, Feihe ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[2] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Zhejiang, Peoples R China

[3] E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 15期

基金：

中国国家自然科学基金;

关键词：

DIRECTED SYNTHESIS; MOLECULAR MECCANO; RING; ROTAXANES; POLYPSEUDOROTAXANES; PSEUDOROTAXANES; CYCLIZATION; CATENATION; MACROCYCLE; CATENANES;

D O I：

10.1021/ol9012052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Taco complex templation based on the bis(m-phenylene)-32-crown-10/paraquat recognition motif is used to develop a general method for preparing mechanically interlocked molecules. A [2]rotaxane and a [2]catenane were synthesized in high yields by a ring-closing metathesis reaction, which was owed to the impactful template effect. Due to the high symmetry of (5,5')-difunctional bis(m-phenylene)-32-crown-10 derivatives, this taco complex templated synthesis has potential to be a tempting method to solve a symmetry-based problem In the fabrication of complicated mechanically interlocked structures.

引用

页码：3350 / 3353

页数：4

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