The Hydrogen Evolution Reaction in Alkaline Solution: From Theory, Single Crystal Models, to Practical Electrocatalysts

被引:1114
|
作者
Zheng, Yao [1 ]
Jiao, Yan [1 ]
Vasileff, Anthony [1 ]
Qiao, Shi-Zhang [1 ,2 ]
机构
[1] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia
[2] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
基金
澳大利亚研究理事会;
关键词
alkaline HER; electrocatalysis; hydrogen adsorption/absorption; hydrogen-evolution reaction; mechanistic studies; 1ST-PRINCIPLES MOLECULAR-DYNAMICS; DENSITY-FUNCTIONAL THEORY; ATOMIC-SCALE SIMULATIONS; WATER DISSOCIATION; PLATINUM SURFACES; ALLOY SURFACES; METAL-SURFACES; ACID-SOLUTIONS; PH-DEPENDENCE; OXIDATION;
D O I
10.1002/anie.201710556
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrogen evolution reaction (HER) is a fundamental process in electrocatalysis and plays an important role in energy conversion for the development of hydrogen-based energy sources. However, the considerably slow rate of the HER in alkaline conditions has hindered advances in water splitting techniques for high-purity hydrogen production. Differing from well documented acidic HER, the mechanistic aspects of alkaline HER are yet to be settled. Acritical appraisal of alkaline HER electrocatalysis is presented, with a special emphasis on the connection between fundamental surface electrochemistry on single-crystal models and the derived molecular design principle for real-world electrocatalysts. By presenting some typical examples across theoretical calculations, surface characterization, and electrochemical experiments, we try to address some key ongoing debates to deliver a better understanding of alkaline HER at the atomic level.
引用
收藏
页码:7568 / 7579
页数:12
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