New developments in catalytic alcohol oxidations for fine chemicals synthesis

被引：622

作者：

Sheldon, RA ^{[1
]}

Arends, IWCE ^{[1
]}

Dijksman, A ^{[1
]}

机构：

[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

CATALYSIS TODAY | 2000年 / 57卷 / 1-2期

关键词：

catalytic oxidations; oxometal and peroxometal pathways; hydrogen peroxide; molecular oxygen; hydrometal pathway;

D O I：

10.1016/S0920-5861(99)00317-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

New developments in liquid phase catalytic oxidations of alcohols with O-2 and H2O2 as the primary oxidant are reviewed. Both homogeneous and heterogeneous catalysts are discussed and compared and emphasis is placed on methods having broad utility for the synthesis of fine chemicals. Mechanistic features of the various systems are also discussed, e.g., oxometal vs. peroxometal pathways in oxidations with H2O2 and oxometal vs. hydridometal pathways with O-2 as the oxidant. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：157 / 166

页数：10

共 66 条

[41]

NEUMANN R, 1995, J AM CHEM SOC, V117, P5074

[42] Pd(OAc)2-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen [J].

Nishimura, T ;

Onoue, T ;

Ohe, K ;

Uemura, S .

TETRAHEDRON LETTERS, 1998, 39 (33) :6011-6014

[43]

NOTARI B, 1987, STUD SURF SCI CATAL, V37, P413

[44] Palladium-catalyzed oxidation of primary and secondary allylic and benzylic alcohols [J].

Peterson, KP ;

Larock, RC .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (10) :3185-3189

[45]

SAKGUCHI S, 1998, B CHEM SOC JPN, V71, P1

[46] CHEMICAL-MODELS OF ENZYMATIC OXIDATION - OXIDATION OF PRIMARY ALCOHOLS IN ALKALINE MEDIA CATALYZED BY COPPER-COMPLEXES [J].

SAKHAROV, AM ;

SKIBIDA, IP .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 48 (2-3) :157-174

[47] Hydrogen peroxide oxidation of benzylic alcohols to benzaldehydes and benzoic acids under halide-free conditions [J].

Sato, K ;

Takagi, J ;

Aoki, M ;

Noyori, R .

TETRAHEDRON LETTERS, 1998, 39 (41) :7549-7552

[48] Organic solvent- and halide-free oxidation of alcohols with aqueous hydrogen peroxide [J].

Sato, K ;

Aoki, M ;

Takagi, J ;

Noyori, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) :12386-12387

[49] OXIDATION OF ALCOHOLS TO ALDEHYDES WITH OXYGEN AND CUPRIC ION, MEDIATED BY NITROSONIUM ION [J].

SEMMELHACK, MF ;

SCHMID, CR ;

CORTES, DA ;

CHOU, CS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (11) :3374-3376

[50]

SEN T, 1996, J CATAL, V163, P979

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