New developments in catalytic alcohol oxidations for fine chemicals synthesis

被引：619
作者：
Sheldon, RA [1 ]
Arends, IWCE [1 ]
Dijksman, A [1 ]
机构：
[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands
来源：
CATALYSIS TODAY | 2000年 / 57卷 / 1-2期
关键词：
catalytic oxidations; oxometal and peroxometal pathways; hydrogen peroxide; molecular oxygen; hydrometal pathway;
D O I：
10.1016/S0920-5861(99)00317-X
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
New developments in liquid phase catalytic oxidations of alcohols with O-2 and H2O2 as the primary oxidant are reviewed. Both homogeneous and heterogeneous catalysts are discussed and compared and emphasis is placed on methods having broad utility for the synthesis of fine chemicals. Mechanistic features of the various systems are also discussed, e.g., oxometal vs. peroxometal pathways in oxidations with H2O2 and oxometal vs. hydridometal pathways with O-2 as the oxidant. (C) 2000 Elsevier Science B.V. All rights reserved.
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页码：157 / 166
页数：10
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