Effects of trace Ca/Sn addition on corrosion behaviors of biodegradable Mg-4Zn-0.2Mn alloy

被引:63
作者
Du, Wenbo [1 ]
Liu, Ke [1 ]
Ma, Ke [1 ]
Wang, Zhaohui [1 ]
Li, Shubo [1 ]
机构
[1] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
基金
北京市自然科学基金;
关键词
Mg-Zn-Mn alloy; Corrosion behaviors; Hank's physiological solution; Electrochemical test; GLASS-FORMING ABILITY; IN-VITRO CORROSION; MECHANICAL-PROPERTIES; MAGNESIUM ALLOYS; HEAT-TREATMENT; DEGRADATION BEHAVIOR; VIVO CORROSION; BINARY-ALLOYS; AS-CAST; ZN;
D O I
10.1016/j.jma.2018.01.004
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The effects of alloying elements of Ca/Sn on corrosion behaviors of the as-cast Mg-4Zn-0.2Mn alloy were investigated by immersion tests and electrochemical methods. The results indicated that the average corrosion rate value of the Mg-4Zn-0.2Mn-Ca alloy was similar to 0.31 mm/year in Hank's physiological solution for 40 days, and corrosion resistance increased for the specimens containing Ca element rather than that containing Sn because of the higher breakdown potential value, lower current density and deactivated corrosion rate, which was ascribed to a formation of the uniformly distributed Mg-Zn-Ca ternary phase. (C) 2018 Published by Elsevier B.V. on behalf of Chongqing University.
引用
收藏
页码:1 / 14
页数:14
相关论文
共 55 条
[1]   The in vivo and in vitro corrosion of high-purity magnesium and magnesium alloys WZ21 and AZ91 [J].
Abidin, Nor Ishida Zainal ;
Rolfe, Barbara ;
Owen, Helen ;
Malisano, Julian ;
Martin, Darren ;
Hofstetter, Joelle ;
Uggowitzer, Peter J. ;
Atrens, Andrej .
CORROSION SCIENCE, 2013, 75 :354-366
[2]  
[Anonymous], WORKSH ABSTR STAT MA
[3]  
[Anonymous], 2004, Standard practice for laboratory immersion corrosion testing of metals
[4]   Mechanical and bio-corrosion properties of quaternary Mg-Ca-Mn-Zn alloys compared with binary Mg-Ca alloys [J].
Bakhsheshi-Rad, H. R. ;
Idris, M. H. ;
Abdul-Kadir, M. R. ;
Ourdjini, A. ;
Medraj, M. ;
Daroonparvar, M. ;
Hamzah, E. .
MATERIALS & DESIGN, 2014, 53 :283-292
[5]   Relationship between the corrosion behavior and the thermal characteristics and microstructure of Mg-0.5Ca-xZn alloys [J].
Bakhsheshi-Rad, H. R. ;
Abdul-Kadir, M. R. ;
Idris, M. H. ;
Farahany, S. .
CORROSION SCIENCE, 2012, 64 :184-197
[6]   Effects of Zn on microstructure, mechanical properties and corrosion behavior of Mg-Zn alloys [J].
Cai, Shuhua ;
Lei, Ting ;
Li, Nianfeng ;
Feng, Fangfang .
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2012, 32 (08) :2570-2577
[7]   The effects of heat treatment and zirconium on the corrosion behaviour of Mg-3Nd-0.2Zn-0.4Zr (wt.%) alloy [J].
Chang, Jian-Wei ;
Fu, Peng-Huai ;
Guo, Xing-Wu ;
Peng, Li-Ming ;
Ding, Wen-Jiang .
CORROSION SCIENCE, 2007, 49 (06) :2612-2627
[8]   Recent advances on the development of magnesium alloys for biodegradable implants [J].
Chen, Yongjun ;
Xu, Zhigang ;
Smith, Christopher ;
Sankar, Jag .
ACTA BIOMATERIALIA, 2014, 10 (11) :4561-4573
[9]   Biomechanical testing and degradation analysis of MgCa0.8 alloy screws: A comparative in vivo study in rabbits [J].
Erdmann, Nina ;
Angrisani, Nina ;
Reifenrath, Janin ;
Lucas, Arne ;
Thorey, Fritz ;
Bormann, Dirk ;
Meyer-Lindenberg, Andrea .
ACTA BIOMATERIALIA, 2011, 7 (03) :1421-1428
[10]   In vitro and in vivo studies on a Mg-Sr binary alloy system developed as a new kind of biodegradable metal [J].
Gu, X. N. ;
Xie, X. H. ;
Li, N. ;
Zheng, Y. F. ;
Qin, L. .
ACTA BIOMATERIALIA, 2012, 8 (06) :2360-2374