Perovskite-type CaMnO3 anode material for highly efficient and stable lithium ion storage

被引:26
作者
Chang, Limin [1 ,2 ]
Li, Jiahui [1 ,2 ]
Le, Zaiyuan [3 ]
Nie, Ping [1 ,2 ]
Guo, Yu [1 ,2 ]
Wang, Hairui [1 ,2 ,4 ]
Xu, Tianhao [1 ,2 ]
Xue, Xiangxin [1 ,2 ]
机构
[1] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Minist Educ, Changchun 130103, Peoples R China
[2] Jilin Normal Univ, Coll Chem, Changchun 130103, Peoples R China
[3] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
[4] Foshan Univ, Sch Mat Sci & Energy Engn, Foshan, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
Perovskite; CaMnO3; Lithium ion batteries; Anode; Different temperature; ORGANOMETAL HALIDE PEROVSKITES; CATHODE MATERIAL; CARBON; ELECTROCATALYST; TRANSITION; ELECTRODES; COMPOSITE; BATTERIES; OXIDES; RICH;
D O I
10.1016/j.jcis.2020.04.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lithium ion batteries are attracting ever increasing attention due to their advantages of high energy/power density, environmental friendly, lifetime and low cost. As a star in the field of materials and energy, perovskites have received extensive attention due to their attracting physical and chemical properties. Herein, CaMnO3, one material from the perovskite family is introduced as a novel anode material for lithium ion batteries, and its electrochemical performance at different temperatures is systematically investigated. CaMnO3 has been synthesized using a liquid phase synthesis method followed by high temperature calcination. The as-obtained CaMnO3 exhibits an initial high discharge capacity of 708.4 mAh g(-1), superior rate capability and stable cycling performance at room temperature, the specific capacity is 102.5 mAh g(-1) after 500 cycles at a current density of 0.1 A g(-1). Additionally, at an extreme temperature of 0 degrees C, the discapacity can reach 138.2 mAh g(-1) at a current density of 0.05 A g(-1). At high temperature of 50 degrees C, the reversible discharge capacity is up to 216.5 mAh g(-1) under the same condition. It is believed that this contribution may lay the foundation for the application of perovskites in other rechargeable batteries and energy storage devices. (C) 2020 Elsevier Inc. All rights reserved.
引用
收藏
页码:698 / 705
页数:8
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