Dinuclear lanthanide(III)/zinc(II) complexes with methyl 2-pyridyl ketone oxime

被引：23
|
作者：
Anastasiadis, Nikolaos C. [1 ,2 ]
Polyzou, Christina D. [1 ,2 ]
Kostakis, George E. [1 ,3 ]
Bekiari, Vlasoula [4 ]
Lan, Yanhua [5 ]
Perlepes, Spyros P. [2 ]
Konidaris, Konstantis F. [1 ]
Powell, Annie K. [1 ,5 ]
机构：
[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany
[2] Univ Patras, Dept Chem, GR-26504 Patras, Greece
[3] Univ Sussex, Dept Chem, Sch Life Sci, Brighton BN1 9QJ, E Sussex, England
[4] Technol Educ Inst Western Greece, Dept Aquaculture, GR-30200 Mesolongion, Greece
[5] Karlsruhe Inst Technol, Inst Inorgan Chem, D-76131 Karlsruhe, Germany
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 46期
关键词：
SINGLE-MOLECULE-MAGNET; ION-MAGNET; DI-2-PYRIDYL KETONE; LANTHANIDE IONS; LUMINESCENT; ZN; RELAXATION; EMISSION; CLUSTERS; BEHAVIOR;
D O I：
10.1039/c5dt03663a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first use of methyl 2-pyridyl ketone oxime (mpkoH) in zinc(II)/lanthanide(III) chemistry leads to the [ZnLn(mpko)(3)(mpkoH)(3)](ClO4)(2) and [ZnLn(NO3)(2)(mpko)(3)(mpkoH)] families of dinuclear Zn(II)Ln(III) complexes displaying blue-green, ligand-based photoluminescence; the (ZnDyIII)-Dy-II compound shows field-induced relaxation of magnetization.
引用
收藏
页码：19791 / 19795
页数：5
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