Durability of metakaolin concrete to sulfate attack

This study investigates the effect of metakaolin (MK) replacement of cement on the durability of concrete to sulfate attack. Three MK replacement levels were considered in the study: 5%, 10%, and 15% by weight of cement. The other experimental parameters investigated in the study were: water to binder ratio (0.5 and 0.6), initial moist curing period (3, 7, and 28 days), curing type (moist and autoclaving), and air content (1.5% and 5%). After the specified initial moist curing period, concrete specimens were immersed in 5% sodium sulfate solution for a total period of 18 month. The degree of sulfate attack was evaluated by measuring expansion of concrete prisms, compressive strength reduction of concrete cubes, and visual inspection of concrete specimens to cracks. The study showed that MK replacement of cement increased the sulfate resistance of concrete. The sulfate resistance of MK concrete increased with increasing the MK replacement level. The sulfate resistance of MK concrete at w/b ratio of 0.5 was found higher than that at w/b ratio of 0.6. Autoclaved MK concrete specimens showed superior sulfate resistance compared to moist cured ones. The pore volume of autoclaved MK concrete was found less than that of moist cured MK concrete. The air entrained MK concrete showed higher improvement in the sulfate resistance than the non-air entrained MK concrete. However, the air entrained plain concrete showed lower improvement in the sulfate resistance than the non-air entrained concrete. (C) 2006 Elsevier Ltd. All rights reserved.