Analysis and simulation of a model of polyelectrolyte gel in one spatial dimension

被引:7
作者
Chen, Haoran [1 ]
Calderer, Maria-Carme [1 ]
Mori, Yoichiro [1 ]
机构
[1] Univ Minnesota, Sch Math, Minneapolis, MN 55455 USA
基金
美国国家科学基金会;
关键词
polyelectrolyte gel; ionic electrodiffusion; two phase model; Onsager's variational principle; stability analysis; HYDROGEL; TRANSPORT; KINETICS; BEHAVIOR; SYSTEM;
D O I
10.1088/0951-7715/27/6/1241
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
We analyse a model of polyelectrolyte gels that was proposed by the authors in previous work. We first demonstrate that the model can be derived using Onsager's variational principle, a general procedure for obtaining equations in soft condensed matter physics. The model is shown to have a unique steady state under the assumption that a suitably defined mechanical energy density satisfies a convexity condition. We then perform a detailed study of the stability of the steady state in the spatially one-dimensional case, obtaining bounds on the relaxation rate. Numerical simulations for the spatially one-dimensional problem are presented, confirming the analytical calculations on stability.
引用
收藏
页码:1241 / 1285
页数:45
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