Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)

被引：28
作者：
Chu, Yu [1 ,2 ,3 ]
Wu, Kui [1 ,2 ]
Su, Xin [1 ,2 ]
Han, Jian [1 ,2 ]
Yang, Zhihua [1 ,2 ]
Pan, Shilie [1 ,2 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
[2] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY | 2018年 / 57卷 / 18期
关键词：
NONLINEAR-OPTICAL MATERIAL; CRYSTAL-STRUCTURES; ETHANE-LIKE; MIDDLE IR; CHALCOHALIDES; SE; CL; BR; SEMICONDUCTOR; FAMILY;
D O I：
10.1021/acs.inorgchem.8b01788
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A suite of quinary thiohalides, ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn), have been successfully synthesized. ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn) undergoes an interesting structural transition from P2(1)/c (alpha phase) to I4/mcm (beta phase), which also leads to obvious disparities on the birefringence from 0.041 (alpha phase) to 0.094 (beta phase). Moreover, the result of deploying a real-space atom-cutting method on ABa(2)MS(4)Cl reveals that their (MS4)(4-) groups may take the major effect in terms of the anisotropy by a structural transition.
引用
收藏
页码：11310 / 11313
页数：4
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