Metal-organic frameworks in seconds via selective microwave heating

被引：73

作者：

Laybourn, Andrea ^{[1
,2
]}

Katrib, Juliano ^{[2
]}

Ferrari-John, Rebecca S. ^{[2
]}

Morris, Christopher G. ^{[1
,3
]}

Yang, Sihai ^{[1
,3
]}

Udoudo, Ofonime ^{[2
]}

Easun, Timothy L. ^{[1
,4
]}

Dodds, Chris ^{[2
]}

Champness, Neil R. ^{[1
]}

Kingman, Samuel W. ^{[2
]}

Schroeder, Martin ^{[1
,3
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Nottingham, Fac Engn, Nottingham NG7 2RD, England

[3] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

[4] Cardiff Univ, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, S Glam, Wales

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2017年 / 5卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

MORPHOLOGY; SIZE; NANOCRYSTALS; TEMPERATURE; FABRICATION; ULTRASOUND; BINDING; SOLIDS; MIL-53; MOF-5;

D O I：

10.1039/c7ta01493g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis of metal-organic framework (MOF) materials via microwave heating often involves shorter reaction times and offers enhanced control of particle size compared to conventional heating. However, there is little understanding of the interactions between electromagnetic waves and MOFs, their reactants, and intermediates, all of which are required for successful scale-up to enable production of commercially viable quantities of material. By examining the effect of average absorbed power with a constant total absorbed energy to prepare MIL-53(Al) we have defined a selective heating mechanism that affords control over MOF particle size range and morphology by altering the microwave power. This is the first time a selective mechanism has been established for the preparation of MOFs via microwave heating. This approach has been applied to the very rapid preparation of MIL-53(Al) ta (62 mg in 4.3 seconds) which represents the fastest reported synthesis of a MOF on this scale to date.

引用

页码：7333 / 7338

页数：6

共 39 条

[31] Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production [J].