(±)-syn-Isopropyl 4-(1,1,1,3,3,3-hexafluoropropan-2-yloxy)-1-hydroxy-3-methyl-2-(prop-1-ynyl)cyclopent-2-enecarboxylate

被引：2

作者：

Gille, Annika ^{[1
]}

Schuermann, Markus ^{[1
]}

Preut, Hans ^{[1
]}

Hiersemann, Martin ^{[1
]}

机构：

[1] Tech Univ Dortmund, Fak Chem, D-44221 Dortmund, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

D O I：

10.1107/S1600536809023162

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C(16)H(18)F(6)O(4), was obtained through an unprecedented one-pot reaction sequence involving a Gosteli-Claisen rearrangement and a cycloisomerization. The constitution and relative configuration were determined by single-crystal X-ray diffraction analysis. In the crystal, molecules are connected via O-H center dot center dot center dot O hydrogen bonds.

引用

页码：01660 / U3169

页数：9

共 7 条

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