Crystal Structure and Catalytic Property of an Oxidomolybdenum(VI) Complex Derived from N'-(2-Hydroxy-3,5-Di-Tert-Butylbenzylidene)-4-Methylbenzohydrazide

被引：8
作者：
Peng, D-L. [1 ,2 ]
机构：
[1] Zhengzhou Univ Light Ind, Sch Mat & Chem Engn, Key Lab Surface & Interface Sci Henan Prov, Zhengzhou, Henan, Peoples R China
[2] Zhengzhou Univ Light Ind, Henan Collaborat Innovat Ctr Environm Pollut Cont, Zhengzhou, Henan, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 03期
关键词：
Schiff base; molybdenum complex; crystal structure; catalytic property; SCHIFF-BASE COMPLEXES; X-RAY-STRUCTURE; OXOPEROXO MOLYBDENUM(VI); TUNGSTEN(VI) COMPLEXES; OLEFIN EPOXIDATION; TERMINAL OXIDANT; HIGHLY EFFICIENT; OXIDATION; SULFIDES; ALCOHOLS;
D O I：
10.1134/S0022476618030125
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
With a tridentate Schiff base ligand N'-(2-hydroxy-3,5-di-tert-butylbenzylidene)-4-methylbenzohydrazide (H2L) and MoO2(acac)(2), an oxidomolybdenum(VI) complex is prepared and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. The complex crystallizes in the monoclinic space group C2/c with unit cell dimensions a = 20.187(2) , b = 7.9094(8) , c = 33.233(3) , beta = 97.394(2)A degrees, V = 5262.1(9) (3), Z = 8, R (1) = 0.0491, and wR (2) = 0.1322. The single crystal X-ray diffraction analysis reveals that the Mo atom is coordinated by NOO donor atoms of the Schiff base ligand, the methanol O atom, and two oxo groups in an octahedral coordination. Catalytic oxidation of the complex on some olefins is performed.
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页码：589 / 594
页数：6
相关论文
共 24 条
  • [1] Molybdenum oxide/bipyridine hybrid material {[MoO3(bipy)][MoO3(H2O)]}n as catalyst for the oxidation of secondary amines to nitrones
    Abrantes, Marta
    Goncalves, Isabel S.
    Pillinger, Martyn
    Vurchio, Carolina
    Cordero, Franca M.
    Brandi, Alberto
    [J]. TETRAHEDRON LETTERS, 2011, 52 (52) : 7079 - 7082
  • [2] Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)]n
    Amarante, Tatiana R.
    Neves, Patricia
    Gomes, Ana C.
    Nolasco, Mariela M.
    Ribeiro-Claro, Paulo
    Coelho, Ana C.
    Valente, Anabela A.
    Paz, Filipe A. Almeida
    Smeets, Stef
    McCusker, Lynne B.
    Pillinger, Martyn
    Goncalves, Isabel S.
    [J]. INORGANIC CHEMISTRY, 2014, 53 (05) : 2652 - 2665
  • [3] Monomeric and dimeric oxido-peroxido tungsten(VI) complexes in catalytic and stoichiometric epoxidation
    Amini, Mojtaba
    Haghdoost, Mohammad Mehdi
    Bagherzadeh, Mojtaba
    [J]. COORDINATION CHEMISTRY REVIEWS, 2014, 268 : 83 - 100
  • [4] [Anonymous], 2015, Acta Crystallogr., V71, P3
  • [5] Molybdenum-oxo chemistry in various aspects of oxygen atom transfer processes
    Arzoumanian, H
    [J]. COORDINATION CHEMISTRY REVIEWS, 1998, 178 : 191 - 202
  • [6] Synthesis, crystal structure and catalytic activity of a novel Mo(VI)-oxazoline complex in highly efficient oxidation of sulfides to sulfoxides by urea hydrogen peroxide
    Bagherzadeh, Mojtaba
    Tahsini, Laleh
    Latifi, Reza
    Ellern, Arkady
    Woo, L. Keith
    [J]. INORGANICA CHIMICA ACTA, 2008, 361 (07) : 2019 - 2024
  • [7] Synthesis, X-ray structure and oxidation catalysis of a oxido-peroxido molybdenum(VI) complex with a tridentate Schiff base ligand
    Bagherzadeh, Mojtaba
    Amini, Mojtaba
    Parastar, Hadi
    Jalali-Heravi, Mehdi
    Ellern, Arkady
    Woo, L. Keith
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 : 86 - 89
  • [8] Catalytic efficiency of a novel complex of oxoperoxo molybdenum(VI): Synthesis, X-ray structure and alkane oxidation
    Bagherzadeh, Mojtaba
    Amini, Mojtaba
    Ellern, Arkady
    Woo, L. Keith
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 15 : 52 - 55
  • [9] Synthesis, characterization and crystal structure of a dioxomolybdenum(VI) complex with a N,O type bidentate Schiff base ligand as a catalyst for homogeneous oxidation of olefins
    Bagherzadeh, Mojtaba
    Latifi, Reza
    Tahsini, Laleh
    Amani, Vahid
    Ellern, Arkady
    Woo, L. Keith
    [J]. POLYHEDRON, 2009, 28 (12) : 2517 - 2521
  • [10] Oxoperoxo molybdenum(VI)- and tungsten(VI) complexes with 1-(2′-hydroxyphenyl) ethanone oxime: Synthesis, structure and catalytic uses in the oxidation of olefins, alcohols, sulfides and amines using H2O2 as a terminal oxidant
    Gharah, Narottam
    Chakraborty, Santu
    Mukherjee, Alok K.
    Bhattacharyya, Ramgopal
    [J]. INORGANICA CHIMICA ACTA, 2009, 362 (04) : 1089 - 1100
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