Rhenium catalysed epoxidations with hydrogen peroxide: tertiary arsines as effective cocatalysts

被引：17

作者：

van Vliet, MCA ^{[1
]}

Arends, IWCE ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 03期

关键词：

D O I：

10.1039/a907975k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perrhenic acid in combination with tertiary arsines gives a versatile catalytic system for epoxidation of alkenes with hydrogen peroxide. The best results are obtained with diphenylmethylarsine. A wide range of alkenes could be epoxidised with aqueous hydrogen peroxide (60%) in 60-100% yields with substrate to catalyst ratios of up to 1000.

引用

页码：377 / 380

页数：4

共 40 条

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