Poly[(μ2-1,3-di-4-pyridylpropane-κ2N:N′)(μ3-glutarato-κ3O:O′:O")-dizinc(II)]

被引：0
作者：
Zhang, Qi-Wei
Wen, Yi-Hang [1 ]
Feng, Yun-Long
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China
[2] Lishui Univ, Dept Chem, Lishui 323000, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷
关键词：
D O I：
10.1107/S0108270106016726
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Zn-2(C5H6O4)(2)(C13H14N2)](n) or [Zn-2(glu)(2)(bpp)](n), is a novel zinc polymer based on mixed flexible glutarate ( glu) and 1,3-di-4-pyridylpropane (bpp) ligands. The Zn-II center has a distorted tetrahedral geometry and the central atom of the bpp ligand is located at a special site with a C-2 axis passing through it. A layer is formed by Zn-glu bonding. Such layers are pillared by bpp ligands, forming a three-dimensional framework with large channels. The inverted interpenetration of two three-dimensional frameworks completes the molecular structure.
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页码：M255 / M257
页数：3
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