Synthesis of heterocycles via group VI Fischer carbene complexes

被引：227
作者：
Barluenga, J [1 ]
Santamaría, J [1 ]
Tomás, M [1 ]
机构：
[1] Univ Oviedo, Inst Univ Quim Organometal E Moles, CSIC, Unidad Asociada, E-33006 Oviedo, Spain
来源：
CHEMICAL REVIEWS | 2004年 / 104卷 / 05期
关键词：
D O I：
10.1021/cr0306079
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal carbene complexes of group 6 are reactive toward a wide array of heteroatom-containing substates, allowing access to a grest variety of mono- and polyheterocycled compounds. In most cases, four- to seven-membered rings are successfully formed in a single step and with high selectivity. Among them, the facile azepine ring formation seems of particular relevance in terms of both mechanistic and synthetic purposes.
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页码：2259 / 2283
页数：25
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