Biomass-derived carbon for ORR: pine needles as a single source for efficient carbon electrocatalyst

被引:19
|
作者
Gao, Jian [1 ]
Chu, Xiujuan [1 ]
He, Chongchong [1 ]
Yin, Zhen [2 ]
Lu, Hongbin [5 ]
Li, Xifei [6 ,7 ]
Feng, Jianyong [3 ,4 ]
Tan, Xiaoyao [1 ]
机构
[1] Tianjin Polytech Univ, Dept Chem Engn, State Key Lab Separat Membranes & Membrane Proc, 399 Binshui West Rd, Tianjin 300387, Peoples R China
[2] Tianjin Univ Sci & Technol, Coll Chem Engn & Mat Sci, 29 13th Ave, Tianjin 300457, Peoples R China
[3] Nanjing Univ, Natl Lab Solid State Microstruct, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Peoples R China
[4] Nanjing Univ, Coll Engn & Appl Sci, Nanjing 210093, Peoples R China
[5] Nantong Univ, Coll Chem & Chem Engn, Nantong 226019, Peoples R China
[6] Xian Univ Technol, Inst Adv Electrochem Energy, Xian Key Lab New Energy Mat & Devices, Xian 710048, Shaanxi, Peoples R China
[7] Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Shaanxi, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Biomass; Oxygen reduction reaction; Non-precious metal catalyst; Fuel cell; Metal-air battery; METAL-FREE ELECTROCATALYSTS; HETEROATOM-DOPED CARBON; OXYGEN-REDUCTION; POROUS CARBON; BIFUNCTIONAL ELECTROCATALYST; FACILE PREPARATION; ACTIVATED CARBON; CATALYSTS; GRAPHENE; NITROGEN;
D O I
10.1007/s10800-020-01483-4
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Oxygen reduction reaction (ORR) is an important electrode reaction for several power sources. However, the reaction is sluggish and expensive noble-metal catalyst are generally needed. The high price of the noble metals has severely hindered the wide application of the related power sources. Therefore, it is a significant challenge to develop the low-cost and efficient non-precious metal electrocatalysts (NPMC) towards ORR. Herein, a typical biomass waste-pine needles has been used as precursor to prepare a porous carbon material, exhibiting superior catalytic activity toward ORR. An onset and half wave potential of similar to 0.96 and 0.72 V(RHE)were obtained in the alkaline solution, respectively. Furthermore, the activity of obtained NPMC can be further improved when it is mixed with the commercial carbon black. Our present results demonstrated that the biomass, such as pine needles, can be employed as promising carbon precursors for NPMC toward ORR.
引用
收藏
页码:1257 / 1267
页数:11
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