CHIRAL IONIC LIQUIDS IN CHIRAL ELECTROPHORETICAL SEPARATIONS

被引:0
作者
Stanescu, Mihai [1 ]
Arama, Corina [1 ]
Monciu, Crina-Maria [1 ]
机构
[1] Carol Davila Univ Med & Pharm, Fac Pharm, Dept Analyt Chem, Bucharest, Romania
关键词
chiral ionic liquids; enantioseparations; capillary electrophoresis; HYDROXYPROPYL-BETA-CYCLODEXTRIN; CAPILLARY-ZONE-ELECTROPHORESIS; LIGAND-EXCHANGE; AMINO-ACIDS; SIMULTANEOUS ENANTIOSEPARATION; SYNERGISTIC SYSTEM; NONAQUEOUS MEDIA; ADDITIVES; CE; SELECTORS;
D O I
暂无
中图分类号
R9 [药学];
学科分类号
1007 ;
摘要
Chiral ionic liquids (CILs) are an important class of chiral selectors that in the last years gained a lot of importance. Their utility in several separation techniques and the relative simple synthesis, allowed them to have multiple applications. Capillary electrophoresis (CE) is an electromigration based technique allowing the analysis of smaller amounts of samples compared to other classical techniques, such as HPLC. Chiral ionic liquids are used in various chiral electromigration techniques for enantioselectivity improvement, since 2006. CILs are rarely used as unique chiral selectors, but some researchers focus on achieving this aim.
引用
收藏
页码:623 / 630
页数:8
相关论文
共 48 条
[1]  
Arama C, 2011, FARMACIA, V59, P34
[2]   Ionic liquids in separation techniques [J].
Berthod, A. ;
Ruiz-Angel, Mt ;
Carda-Broch, S. .
JOURNAL OF CHROMATOGRAPHY A, 2008, 1184 (1-2) :6-18
[3]   Chiral recognition mechanisms [J].
Berthod, A .
ANALYTICAL CHEMISTRY, 2006, 78 (07) :2093-2099
[4]   Synthesis and characterization of novel chiral ionic liquids and investigation of their enantiomeric recognition properties [J].
Bwambok, David K. ;
Marwani, Hadi M. ;
Fernand, Vivian E. ;
Fakayode, Sayo O. ;
Lowry, Mark ;
Negulescu, Ioan ;
Strongin, Robert M. ;
Warner, Isiah M. .
CHIRALITY, 2008, 20 (02) :151-158
[5]   Combined Use of Ionic Liquid and Hydroxypropyl-β-Cyclodextrin for the Enantioseparation of Ten Drugs by Capillary Electrophoresis [J].
Cui, Yan ;
Ma, Xiaowei ;
Zhao, Min ;
Jiang, Zhen ;
Xu, Shuying ;
Guo, Xingjie .
CHIRALITY, 2013, 25 (07) :409-414
[6]   Ephedrinium-Based Protic Chiral Ionic Liquids for Enantiomeric Recognition [J].
de Rooy, Sergio L. ;
Li, Min ;
Bwambok, David K. ;
El-Zahab, Bilal ;
Challa, Santhosh ;
Warner, Isiah M. .
CHIRALITY, 2011, 23 (01) :54-62
[7]   Chiral ionic liquids: Synthesis and applications [J].
Ding, J ;
Armstrong, DW .
CHIRALITY, 2005, 17 (05) :281-292
[8]   Chiral ionic liquids as stationary phases in gas chromatography [J].
Ding, J ;
Welton, T ;
Armstrong, DW .
ANALYTICAL CHEMISTRY, 2004, 76 (22) :6819-6822
[9]  
Draghici I, 2013, FARMACIA, V61, P229
[10]   Diels-Alder reactions in ionic liquids - A safe recyclable alternative to lithium perchlorate-diethyl ether mixtures [J].
Earle, MJ ;
McCormac, PB ;
Seddon, KR .
GREEN CHEMISTRY, 1999, 1 (01) :23-25