Colored Supramolecular Host System Using a Charge-Transfer Complex Composed of 1,1′-Bi-2-naphthol and 2,5-Substituted 1,4-Benzoquinone

被引：14

作者：

Imai, Yoshitane ^{[1
]}

Kamon, Kensaku ^{[1
]}

Kinuta, Takafumi ^{[1
]}

Sato, Tomohiro ^{[2
]}

Tajima, Nobuo ^{[3
]}

Kuroda, Reiko ^{[2
,4
]}

Matsubara, Yoshio ^{[1
]}

机构：

[1] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Osaka 5778502, Japan

[2] JST ERATO SORST Kuroda Chiromorphol Team, Meguro Ku, Tokyo 1530041, Japan

[3] NIMS, Computat Mat Sci Ctr, Principles Simulat Grp 1, Tsukuba, Ibaraki 3050047, Japan

[4] Univ Tokyo, Dept Life Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 2009卷 / 15期

关键词：

Charge transfer; Host-guest systems; Molecular recognition; Quinones; CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; SOLID-STATE CRYSTALLIZATION; BIS-BETA-NAPHTHOL; CHIRAL RECOGNITION; INCLUSION; BENZOQUINONE; DERIVATIVES; 10,10'-DIHYDROXY-9,9'-BIPHENANTHRYL;

D O I：

10.1002/ejoc.200900004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A colored, two-component, supramolecular, host system has been developed. This supramolecular host system uses a charge-transfer (CT) complex composed of racemic (rac)-1,1'-bi-2-naphthol, which acts as an electron donor, and 2,5-substituted 1,4-benzoquinone, which acts as an electron acceptor. This CT host system can selectively include aromatic guest molecules into a channel-like cavity by tuning the packing of the electron-donor and electron-acceptor molecules. Characteristically, the color and diffuse reflectance spectra (DRS) of the inclusion CT complex can be tuned by changing the type of the component 2,5-substituted 1,4-benzoquinone. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2519 / 2525

页数：7

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