Ag3PO4 nanoparticle decorated on SiO2 spheres for efficient visible light photocatalysis

被引:35
作者
Sharma, Manu [1 ]
Ojha, Kasinath [1 ]
Ganguly, Aparna [2 ]
Ganguli, Ashok K. [1 ,3 ]
机构
[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India
[2] Indian Inst Technol, Nanoscale Res Facil, New Delhi 110016, India
[3] Inst Nano Sci Sc Technol, Habitat Ctr, Mohali 160062, Punjab, India
关键词
HIGHLY EFFICIENT; SILVER PHOSPHATE; PORE-SIZE; COMPOSITE; DEGRADATION; SILICA; SEMICONDUCTOR; MICROCRYSTALS; PERFORMANCE; FABRICATION;
D O I
10.1039/c5nj01157d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A visible light active photocatalyst, Ag3PO4 (20 nm), in combination with mesoporous SiO2 spheres (200 nm) leads to enhanced photocatalytic activity (similar to 52 times) in the photocatalytic degradation of Rhodamine B dye compared to bare silver phosphate. The lifetime of the charge carriers is increased by nearly four times (from 0.05 to 0.20 ns) in the composite. The silver phosphate-silica composite has almost no loss of activity after 5 cycles under light irradiation, indicating that the composite has good photocatalytic stability. The addition of SiO2 also reduces the cost of the composite catalyst.
引用
收藏
页码:9242 / 9248
页数:7
相关论文
共 46 条
[1]  
Antonietti M, 1998, ADV MATER, V10, P154, DOI 10.1002/(SICI)1521-4095(199801)10:2<154::AID-ADMA154>3.0.CO
[2]  
2-I
[3]   Two-dimensional dendritic Ag3PO4 nanostructures and their photocatalytic properties [J].
Bi, Yingpu ;
Hu, Hongyan ;
Jiao, Zhengbo ;
Yu, Hongchao ;
Lu, Gongxuan ;
Ye, Jinhua .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (42) :14486-14488
[4]   Facile synthesis of rhombic dodecahedral AgX/Ag3PO4 (X = Cl, Br, I) heterocrystals with enhanced photocatalytic properties and stabilities [J].
Bi, Yingpu ;
Ouyang, Shuxin ;
Cao, Junyu ;
Ye, Jinhua .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (21) :10071-10075
[5]   Facet Effect of Single-Crystalline Ag3PO4 Sub-microcrystals on Photocatalytic Properties [J].
Bi, Yingpu ;
Ouyang, Shuxin ;
Umezawa, Naoto ;
Cao, Junyu ;
Ye, Jinhua .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (17) :6490-6492
[6]   Large-scale synthesis of uniform silver orthophosphate colloidal nanocrystals exhibiting high visible light photocatalytic activity [J].
Cao-Thang Dinh ;
Thanh-Dinh Nguyen ;
Kleitz, Freddy ;
Trong-On Do .
CHEMICAL COMMUNICATIONS, 2011, 47 (27) :7797-7799
[7]  
Cuia H., 2013, MATER LETT, V93, P28
[8]   Silica Mesostructures: Control of Pore Size and Surface Area Using a Surfactant-Templated Hydrothermal Process [J].
Ganguly, Aparna ;
Ahrnad, Tokeer ;
Ganguli, Ashok K. .
LANGMUIR, 2010, 26 (18) :14901-14908
[9]   Ag3PO4/In(OH)3 Composite Photocatalysts with Adjustable Surface-Electric Property for Efficient Photodegradation of Organic Dyes under Simulated Solar-Light Irradiation [J].
Guo, Jianjun ;
Ouyang, Shuxin ;
Zhou, Han ;
Kako, Tetsuya ;
Ye, Jinhua .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (34) :17716-17724
[10]   Double-layered composite particles as a complex stationary phase for high-performance liquid chromatography [J].
Honda, F ;
Honda, H ;
Koishi, M ;
Matsuno, T .
JOURNAL OF CHROMATOGRAPHY A, 1997, 775 (1-2) :13-27