The XB(C6F5)2 Halogenoborane Route to Phosphole Derivatives

被引：2

作者：

Moericke, Jennifer ^{[1
]}

Ueno, Atsushi ^{[1
]}

Wibbeling, Birgit ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 2019卷 / 24期

关键词：

Synthesis design; Halogenoboranes; Carboboration; Phospholes; Structure elucidation; MAIN-GROUP ELEMENTS; METALLACYCLE TRANSFER; ORGANIC-CHEMISTRY; LONE-PAIR; 1,1-ORGANOBORATION; ORGANOBORATION; HALOBORATION; REACTIVITY; 1,1-CARBOBORATION; HETEROCYCLES;

D O I：

10.1002/ejic.201900505

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of dimesityl(propynyl)phosphane (9) with either of the halogeno-B(C6F5)(2) reagents 10a,b (hal: Cl, Br) proceeds through addition and rearrangement to give the unsaturated C-2-bridged Hal-P/B Lewis pairs 12a,b. Their reactions with two molar equiv. of a small series of alkynyllithium reagents R-C equivalent to CLi led to the formation of the phosphole derivatives 17 via intramolecular 1,1-carboboration reaction.

引用

页码：2912 / 2917

页数：6

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