Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc

被引：32
|
作者：
Shibata, T [1 ]
Nakatsui, K [1 ]
Soai, K [1 ]
机构：
[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
来源：
INORGANICA CHIMICA ACTA | 1999年 / 296卷 / 01期
关键词：
enantioselective catalysis; alkylation; zinc complexes; alkenyl complexes;
D O I：
10.1016/S0020-1693(99)00300-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Diisopropenylzinc adds highly enantioselectively to various aldehydes in the presence of a catalytic amount of chiral amino alcohols to give enantiomerically enriched allyl alkanols with up to 92% e.e. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：33 / 36
页数：4
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