Palladium-catalyzed synthesis of mixed anhydrides via carbonylative telomerization

被引:6
|
作者
Hares, Kevin [1 ]
Vogelsang, Dennis [1 ]
Wernsdoerfer, Charlotte S. [1 ]
Panke, Dennis [1 ]
Vogt, Dieter [1 ]
Seidensticker, Thomas [1 ]
机构
[1] TU Dortmund Univ, Dept Biochem & Chem Engn, Lab Ind Chem, Dortmund, Germany
关键词
ACID; BUTADIENE; ESTERS; ISOMERIZATION; CARBOXYLATES; EFFICIENT; STEP;
D O I
10.1039/d2cy00486k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For the first time, mixed carboxylic anhydrides were accessed directly via homogeneous palladium catalysis from 1,3-butadiene and carboxylic acids. Under carbonylative telomerization conditions, the respective mixed 3,8-nonadienoic anhydrides are formed in a single reaction step with yields of up to 82%. These very reactive mixed anhydrides can then be used for consecutive reactions in a one-pot manner and selectively transfer the newly formed unsaturated C9 unit. Possible changes in the proposed mechanism were discussed and in a first example, the mixed anhydrides were utilized to form amides.
引用
收藏
页码:3992 / 4000
页数:9
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