Synthesizing low-cost, high-corrosion-resistant refractory kiln furniture for the calcination of Li-ion battery cathode materials

被引:16
作者
Wang, Hailu [1 ]
Li, Shujing [1 ,2 ]
Li, Yuanbing [1 ,2 ]
Xiang, Ruofei [1 ,2 ]
Yuan, Lin [3 ]
Luo, Han [1 ]
Xu, Nana [1 ]
Zhou, Zimeng [1 ]
机构
[1] Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, Wuhan 430081, Peoples R China
[2] Wuhan Univ Sci & Technol, Natl Prov Joint Engn Res Ctr High Temp Mat & Lini, Wuhan 430081, Peoples R China
[3] Ruitai Mat Technol Co Ltd, Beijing 100024, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
Mullite; Corrosion; Refractories; ELECTROCHEMICAL PROPERTIES; WASTE; ZIRCONIA; MULLITE; TRANSFORMATION; EVOLUTION; CERAMICS;
D O I
10.1016/j.ceramint.2020.09.276
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In recent years, the rapid development of the ternary Li-ion battery cathode Li(NixCoyMnz)O-2 (LNCM) materials industry has resulted in increased demand for refractory kiln furniture (saggars). To reduce the production cost of the saggars and improve their anti-corrosion performance, mullite-zirconia materials were synthesized from zircon-containing kyanite tailings. This study examines the potential of the materials as saggars in the preparation of the LNCM materials based on two aspects-the material's physical properties and its resistance to the corrosion of LNCM materials. The results show that mullite-zirconia composites can be successfully synthesized at 1500-1600 degrees C, and the physical properties of the materials meet the needs of production. Additionally, the mullite-zirconia material prepared at 1550 degrees C was more resistant to LCNM precursor corrosion than the ones prepared at 1500 and 1600 degrees C.
引用
收藏
页码:4049 / 4054
页数:6
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