Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions

被引：8

作者：

Harrowfield, Jack M. ^{[1
,2
]}

Ling, Irene ^{[3
]}

Skelton, Brian W. ^{[1
]}

Sobolev, Alexandre N. ^{[1
]}

White, Allan H. ^{[1
]}

机构：

[1] Univ Western Australia, Sch Chem & Biochem, 35 Stirling Highway, Crawley, WA 6009, Australia

[2] Univ Strasbourg, Inst Sci & Ingn Supramol, 8 Allee Gaspard Monge, F-67083 Strasbourg, France

[3] Monash Univ Malaysia, Sch Sci, Jalan Lagoon Selatan, Bandar Sunway 47500, Selangor, Malaysia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2017年 / 70卷 / 05期

关键词：

RARE-EARTH CARBOXYLATES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; COMPLEXES; LUMINESCENCE; SPECTROSCOPY;

D O I：

10.1071/CH16584

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extended structural studies, largely determinations at similar to 150 K, of the family of hydrates of [Co(NH3)(6)][Ln(dipic)(3)] (Ln = La-Lu, and Y; dipic = dipicolinate = pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature of the interactions between the formally achiral cation and the chiral anions. They also provide a reference point for consideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.

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页码：485 / 493

页数：9

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