Geologically-inspired strong bulk ceramics made with water at room temperature

被引:173
作者
Bouville, Florian [1 ]
Studart, Andre R. [1 ]
机构
[1] Swiss Fed Inst Technol, Dept Mat, Complex Mat, CH-8093 Zurich, Switzerland
基金
瑞士国家科学基金会;
关键词
PRESSURE SOLUTION; CALCITE; COMPACTION; VATERITE;
D O I
10.1038/ncomms14655
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Dense ceramic materials can form in nature under mild temperatures in water. By contrast, man-made ceramics often require sintering temperatures in excess of 1,400 degrees C for densification. Chemical strategies inspired by biomineralization processes have been demonstrated but remain limited to the fabrication of thin films and particles. Besides biomineralization, the formation of dense ceramic-like materials such as limestone also occurs in nature through large-scale geological processes. Inspired by the geological compaction of mineral sediments in nature, we report a room-temperature method to produce dense and strong ceramics within timescales comparable to those of conventional manufacturing processes. Using nanoscale powders and high compaction pressures, we show that such cold sintering process can be realized with water at room temperature to result in centimetre-sized bulk parts with specific strength that is comparable to, and occasionally even higher than, that of traditional structural materials like concrete.
引用
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页数:8
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