Preparations, structures and electrical conductivities of oxidized bulky [M(C3S5)(3)]-type anion complexes [C3S52- = 4,5-disulfanyl-1,3-dithiole-2-thionate(2-)]

被引：3

作者：

Matsubayashi, GE

Nakano, M

Tamura, H

Natsuaki, K

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Toyonaka, Osaka 560, 1-16, Machikaneyama

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1997年 / 296卷

关键词：

dithiolate; C3S5; metal complex; structure; electrical conductivity;

D O I：

10.1080/10587259708032324

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Several [M(C3S5)(3)](n-) (M = V(IV), Mo(IV), W(IV); n = 2 and M = Nb(V), Re(V); n = 1) anion complexes were prepared. They exhibited low oxidation potentials of +0.145 - +0.76 V vs. SCE. They were oxidized by reactions with iodine, [Fe(C5Me5)2](+), [Fe(C5H5)2]+, and the TTF.+ radical cation, as well as the electrolysis, in organic solvents to afford oxidized [M(C3S5)3](m-) (0 < m < 1) species having electrical conductivities of 6.0 x 10(-5) - 1.5 x 10(-1) S cm(-1) measured for compacted pellets at room temperature. X-ray crystal structures of the [M(C3S5)(3)](2-) (M = Mo, W) complexes and the one-electron-oxidized [M(C3S5)3](-) (M = V, W) species as well as ESR and X-ray photoelectron spectra of the oxidized species are discussed.

引用

页码：245 / 253

页数：9

共 15 条

[1]

BENETT MJ, 1973, J AM CHEM SOC, V95, P7504

[2] CONDUCTIVE MOLECULAR-CRYSTALS FROM 3-DIMENSIONAL BUILDING-BLOCKS - SYNTHESIS AND CHARACTERIZATION OF TRIS(BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM) BIS(TRIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)VANADATE), [ET]3[V(DMIT)3]2, AND THE CORRESPONDING TETRAMETHYLTETRASELENFULVALENIUM SALT [J].

BRODERICK, WE ;

MCGHEE, EM ;

GODFREY, MR ;

HOFFMAN, BM ;

IBERS, JA .

INORGANIC CHEMISTRY, 1989, 28 (15) :2902-2904

[3] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].

CASSOUX, P ;

VALADE, L ;

KOBAYASHI, H ;

KOBAYASHI, A ;

CLARK, RA ;

UNDERHILL, AE .

COORDINATION CHEMISTRY REVIEWS, 1991, 110 (01) :115-160

[4] X-RAY MOLECULAR-STRUCTURE OF [NBU(N)4]2[MO(C3S5)3] AND ELECTRICAL CONDUCTIVITIES OF THE OXIDIZED SPECIES [J].

MATSUBAYASHI, G ;

DOUKI, K ;

TAMURA, H .

CHEMISTRY LETTERS, 1992, (07) :1251-1254

[5] PREPARATION, SPECTROSCOPY AND OXIDATION OF [RE(C3S5)3]- AND [REO(C3S5)2]- COMPLEXES AND CRYSTAL-STRUCTURE OF [PPH4][REO(C3S5)2] [J].

MATSUBAYASHI, G ;

MAIKAWA, T ;

NAKANO, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (20) :2995-2999

[6] SPECTROSCOPIC AND ELECTRICAL-PROPERTIES OF VO (2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATE)2 AND V (2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATE)3 ANION COMPLEXES AND X-RAY CRYSTAL-STRUCTURE OF [N-METHYLPHENAZINIUM]2[V(2-THIOXO-1,3-DITHIOLE-4,5-DITHOLATE(3] [J].

MATSUBAYASHI, G ;

AKIBA, K ;

TANAKA, T .

INORGANIC CHEMISTRY, 1988, 27 (26) :4744-4749

[7] SPECTROSCOPY AND ELECTRICAL-CONDUCTIVITY OF [AU(C3S5)2]N- AND [AU(C3SE5)2]N- (N = 0-1) COMPLEXES AND X-RAY CRYSTAL-STRUCTURE OF [NBUN4][AU(C3S5)2] [J].

MATSUBAYASHI, G ;

YOKOZAWA, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11) :3535-3539

[8] SYNTHESES AND SPECTROSCOPIC AND ELECTRICAL-PROPERTIES OF [W(C3S5)(3)](2-) AND [MO(C3S5)(3)](2-) ANION COMPLEXES AND THEIR OXIDIZED SPECIES AND X-RAY CRYSTAL-STRUCTURES OF [NBU(4)(N)](2)[W(C3S5)(3)],[NBU4N](2)[MO(C3S5)(3)], AND [FE(C(5)ME(5))(2)][W(C3S5)(3)] [J].

MATSUBAYASHI, G ;

DOUKI, K ;

TAMURA, H ;

NAKANO, M ;

MORI, W .

INORGANIC CHEMISTRY, 1993, 32 (26) :5990-5996

[9]

MATSUBAYASHI G, 1991, REV HETEROATOM CHEM, V4, P171

[10]

MATSUBAYASHI G, 1989, INORG CHIM ACTA, V165, P245

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