Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-diene dithiocyanate with Nickel (II) acetate

被引:1
作者
Ishak, Nur Iliyani Mohd [1 ]
Yamin, Bohari M. [1 ]
机构
[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Dept Chem, Bangi 43600, Selangor, Malaysia
来源
2013 UKM FST POSTGRADUATE COLLOQUIUM | 2013年 / 1571卷
关键词
Tetraaza; spectroscopic studies; X-Ray crystallography;
D O I
10.1063/1.4858771
中图分类号
O59 [应用物理学];
学科分类号
摘要
The complexation of nickel acetate with tetraaza involves deprotonation of protonated amine nitrogen to form neutral ligand coordinated to the nickel via the four nitrogen atom. The dication complex is paired with thiocyanate anions. The complex was characterized by elemental analysis, UV-VIS and FTIR spectroscopic method. The crystal structure of nickel complex characterized by X-Ray crystallography and adopts square planar geometry.
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页码:918 / 925
页数:8
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