Templated self- assembly of ordered mesoporous silica on clay nanotubes

被引:51
|
作者
Glotov, Aleksandr [1 ]
Levshakov, Nikolay [1 ]
Stavitskaya, Anna [1 ]
Artemova, Maria [1 ]
Gushchin, Pavel [1 ]
Ivanov, Evgenii [1 ]
Vinokurov, Vladimir [1 ]
Lvov, Yuri [1 ,2 ]
机构
[1] Gubkin Russian State Univ Oil & Gas, Dept Phys & Colloid Chem, Moscow 119991, Russia
[2] Louisiana Tech Univ, Inst Micromfg, Ruston, LA 71272 USA
关键词
MECHANICAL STABILITY; HALLOYSITE NANOTUBES; MCM-41; SHELL; ADSORPTION; DEPOSITION; ADDITIVES; RUTHENIUM; CATALYSIS; SUPPORT;
D O I
10.1039/c9cc01935a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel self-assembly strategy of ordered silica arrays on halloysite clay nanotubes allows us to obtain mesoporous MCM-41 materials with enhanced thermal and mechanical stability. The formation of a structured mesoporous silica phase on halloysite is based on the assembly of cationic amphiphilic molecules onto a negative nanotube surface. The resulting MCM-41/halloysite composite demonstrated thermal and mechanical stability up to 1100 degrees C and 500 MPa showing great potential for application of mesoporous materials as industrial catalyst carriers and adsorbents.
引用
收藏
页码:5507 / 5510
页数:4
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