Intramolecular Diels-Alder reactions with 6-hydroxypyranone as dienophile

被引：0
作者：
Richter, F
Maichle-Mössmer, C
Maier, ME
机构：
[1] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany
[2] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
来源：
SYNLETT | 2002年 / 07期
关键词：
furfuryl alcohol; intramolecular Diels-Alder; pyranone; decalin; oxidative rearrangement;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidative rearrangement of furfuryl alcohols carrying an appropriately positioned dienyl side chain provided hydroxypyranone intermediates that underwent a subsequent intramolecular Diels-Alder reaction. The heterocyclic ring of the tricyclic cycloadducts opened via ring chain tautomerism to highly functionalized decalin or hexahydroindene derivatives, respectively. In one instance, that is compound 6 the structure was secured by X-ray analysis.
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页码：1097 / 1100
页数：4
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