Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts

被引：70

作者：

Klingshirn, MA

Broker, GA

Holbrey, JD

Shaughnessy, KH

Rogers, RD

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[2] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 13期

关键词：

D O I：

10.1039/b203367d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium-catalyzed copolymerization of styrene and CO in an ionic liquid solvent, 1-hexylpyridinium bis(trifluoromethanesulfonyl) imide, gave improved yields and increased molecular weights compared to polymerizations run in methanol.

引用

页码：1394 / 1395

页数：2

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