Crystal structure of hexa(μ-bromo)-μ4-oxo-tetrakis-(1-ethyltetrazole)-tetracopper(II)

被引：2

作者：

Virovets, AV ^{[1
]}

Bikzhanova, GA ^{[1
]}

Lavrenova, LG ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2001年 / 42卷 / 06期

关键词：

D O I：

10.1023/A:1015012903740

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the [Cu-4(mu-Br)(6)(mu(4)-O)(ettz)(4)] complex of the monoclinic crystal system was investigated by X-ray diffraction analysis: a = 45.016(12), b = 9.363(4), c = 15.698(5) Angstrom, 100.28(2)degrees, V-cell = 6510(4) Angstrom(3), space group C2/c, Z = 8, p(calc) = 2.330 g/cm(3), R1 = 0.0697 for 714 F-hlk greater than or equal to 4sigma(F). The copper atoms form a tetrahedron with an oxygen atom in the middle and bromine atoms on the edges. The coordination polyhedron around the copper atom is a distorted trigonal bipyramid (CuOBr3N unit). All tetrazole ligands are monodentate and coordinated by the N-4 atoms.

引用

页码：989 / 994

页数：6

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