A new fullerene-like inorganic compound fabricated by the sonolysis of an aqueous solution of TlCl3

被引:51
作者
Avivi, S
Mastai, Y
Gedanken, A [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-53900 Ramat Gan, Israel
[2] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel
关键词
D O I
10.1021/ja993109j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The sonication of an aqueous solution of TlCl3 under a flow of argon has led to a precipitate, which is composed of two products. The major product is Tl2OCl2, while Tl2O is obtained in small quantities. The later has a structure of a multi-shell closed compound. The identification of the inorganic fullerenes in the TEM picture as the thallium(I) oxide is based on SAED measurements.
引用
收藏
页码:4331 / 4334
页数:4
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