Pincer Complexes with Thione Sulfur Donors

被引：14

作者：

Aleksanyan, Diana V. ^{[1
]}

Kozlov, Vladimir A. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Ul Vavilova 28, Moscow 119991, Russia

来源：

PRIVILEGED PINCER-METAL PLATFORM: COORDINATION CHEMISTRY & APPLICATIONS | 2016年 / 54卷

基金：

俄罗斯基础研究基金会;

关键词：

Catalysis; Cyclometallation; Luminescence; Organothiophosphorus compounds; Pincer complexes; Sulfur donors; Thioamides; SECONDARY THIOAMIDE UNITS; PALLADIUM COMPLEXES; PLATINUM COMPLEXES; CATALYTIC PERFORMANCE; RUTHENIUM COMPLEXES; MOLECULAR-STRUCTURE; OPTICAL-PROPERTIES; LIGAND BACKBONE; SCS; BOND;

D O I：

10.1007/3418_2015_115

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rapid development of pincer chemistry over the last several decades made a substantial contribution in extension of theoretical and practical organometallic chemistry as well as organic synthesis, catalysis, and materials science. This review is devoted to relatively new types of nonclassical pincer compounds bearing thione sulfur donors incorporated into thiophosphoryl and/or thioamide groups. The discussion is focused on synthetic aspects and structural features of symmetrical and hybrid S,C,S-pincer ligands and complexes with particular attention to the practically valuable properties.

引用

页码：209 / 238

页数：30

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