Fast, Ambient Temperature and Pressure lonothermal Synthesis of Three-Dimensional Covalent Organic Frameworks

被引：330

作者：

Guan, Xinyu ^{[1
]}

Ma, Yunchao ^{[1
]}

Li, Hui ^{[1
]}

Yusran, Yusran ^{[1
]}

Xue, Ming ^{[1
]}

Fang, Qianrong ^{[1
]}

Yan, Yushan ^{[2
]}

Valtchev, Valentin ^{[1
,3
]}

Qiu, Shilun ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

[2] Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA

[3] Normandie Univ, Lab Catalyse & Spectrochim, ENSICAEN, UNICAEN,CNRS, 6 Marechal Juin, F-14050 Caen, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 13期

基金：

中国国家自然科学基金;

关键词：

CRYSTALLINE; CONSTRUCTION; STABILITY;

D O I：

10.1021/jacs.8b01320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent organic frameworks (COFs) are an emerging class of porous crystalline polymers with wide range of potential applications. However, the availability of three-dimensional (3D) COFs is still limited, and their synthesis is confined to the high-temperature solvothermal method. Here, we report for the first time a general and simple strategy to produce a series of 3D ionic liquid (IL) containing COFs (3D-IL-COFs) by using IL as a green solvent. The syntheses are carried out at ambient temperature and pressure accompanied by a high reaction speed (e.g., only three mins for 3D-IL-COF-1), and the IL can be reused without activity loss. Furthermore, the 3DIL-COFs show impressive performance in the separation of CO2/N-2 and CO2/CH4. This research thus presents a potential pathway to green large-scale industrial production of COFs.

引用

页码：4494 / 4498

页数：5

共 35 条

[1]

Beaudoin D, 2013, NAT CHEM, V5, P830, DOI [10.1038/NCHEM.1730, 10.1038/nchem.1730]

[2] Extraction of Photogenerated Electrons and Holes from a Covalent Organic Framework Integrated Heterojunction [J].

Calik, Mona ;

Auras, Florian ;

Salonen, Laura M. ;

Bader, Kathrin ;

Grill, Irene ;

Handloser, Matthias ;

Medina, Dana D. ;

Dogru, Mirjam ;

Loebermann, Florian ;

Trauner, Dirk ;

Hartschuh, Achim ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (51) :17802-17807

[3] Rationally synthesized two-dimensional polymers [J].

Colson, John W. ;

Dichtel, William R. .

NATURE CHEMISTRY, 2013, 5 (06) :453-465

[4] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[5] Three-periodic nets and tilings: edge-transitive binodal structures [J].

Delgado-Friedrichs, Olaf ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2006, 62 :350-355

[6] The atom, the molecule, and the covalent organic framework [J].

Diercks, Christian S. ;

Yaghi, Omar M. .

SCIENCE, 2017, 355 (6328)

[7] Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction [J].

Ding, San-Yuan ;

Gao, Jia ;

Wang, Qiong ;

Zhang, Yuan ;

Song, Wei-Guo ;

Su, Cheng-Yong ;

Wang, Wei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) :19816-19822

[8]

Doonan CJ, 2010, NAT CHEM, V2, P235, DOI [10.1038/nchem.548, 10.1038/NCHEM.548]

[9] Ionic Covalent Organic Frameworks with Spiroborate Linkage [J].

Du, Ya ;

Yang, Haishen ;

Whiteley, Justin Michael ;

Wan, Shun ;

Jin, Yinghua ;

Lee, Se-Hee ;

Zhang, Wei .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (05) :1737-1741

[10] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

← 1 2 3 4 →