Charge-transfer emission in nonplanar three-coordinate organoboron compounds for fluorescent sensing of fluoride

被引:327
作者
Liu, Xiang Yang [1 ]
Bai, Dong Ren [1 ]
Wang, Suning [1 ]
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
关键词
boron; charge transfer; fluorescence; fluorides; sensors;
D O I
10.1002/anie.200601286
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A real turn-on: Two nonplanar three-coordinate boron compounds were synthesized as fluorescent sensors for fluoride that utilize charge-transfer emission. The fluorescence of one of the sensors turns on (see picture) and the other turns off in the presence of fluoride. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5475 / 5478
页数:4
相关论文
共 55 条
  • [1] Multidentate Lewis acids: synthesis, structure and mode of action of a redox-based fluoride ion sensor
    Aldridge, S
    Bresner, C
    Fallis, IA
    Coles, SJ
    Hursthouse, MB
    [J]. CHEMICAL COMMUNICATIONS, 2002, (07) : 740 - 741
  • [2] [Anonymous], ANGEW CHEM
  • [3] Dipyrrolylquinoxalines: Efficient sensors for fluoride anion in organic solution
    Black, CB
    Andrioletti, B
    Try, AC
    Ruiperez, C
    Sessler, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (44) : 10438 - 10439
  • [4] CONNORS KA, BINDIN CONSTANTS, P1987
  • [5] Selective fluorescence detection of fluoride using boronic acids
    Cooper, CR
    Spencer, N
    James, TD
    [J]. CHEMICAL COMMUNICATIONS, 1998, (13) : 1365 - +
  • [6] A novel class of emitting amorphous molecular materials with bipolar character for electroluminescence
    Doi, H
    Kinoshita, M
    Okumoto, K
    Shirota, Y
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (05) : 1080 - 1089
  • [7] Dreisbuch R. H., 1980, HDB POISONING
  • [8] Emsley J., 2000, SORDID TALE MURDER F
  • [9] Entwistle C. D., 2002, ANGEW CHEM, V114, P3051
  • [10] Applications of three-coordinate organoboron compounds and polymers in optoelectronics
    Entwistle, CD
    Marder, TB
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (23) : 4574 - 4585