Hydrogenation of Ketones and Esters Catalyzed by Pd/CaEuro'SiO2

被引：3

作者：

Akchurin, T. I. ^{[1
]}

Baibulatov, N. Z. ^{[1
]}

Dokichev, V. A. ^{[2
]}

机构：

[1] Russian Acad Sci, Ufa Inst Chem, Ufa, Russia

[2] Ufa State Aviat Tech Univ, Ul K Marksa 12, Ufa 450008, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 02期

关键词：

heterogeneous catalysis; carbon-silica carrier; hydrogenation; unsaturated ketones; unsaturated esters; CHEMOSELECTIVE HYDROGENATION;

D O I：

10.1134/S1070363218020032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of unsaturated ketones and esters with molecular hydrogen on the 5%Pd/CaEuro'SiO2 heterogeneous catalyst has been studied. The reaction direction and yield are determined by the starting compounds structure. Hydrogenation of unsaturated ketones containing phenyl group at the double carbon-carbon atom is accompanied by the reduction of the ketone group into the alcohol one. Hydrogenation of unsaturated esters is accompanied by transesterification.

引用

页码：195 / 198

页数：4

共 19 条

[1] Alkene hydrogenation over palladium supported on a carbon-silica material [J].