Elucidation of the Nanoparticle Effect on the Grafting of Vinyl Monomers onto Cotton Fabric

The grafting emulsion polymerization of vinyl monomers onto cotton was carried Out in the presence of double-modified montmorillonite clay. The obtained results show that grafting with glycidyl methacrylate/montmorillonite gave a higher rate of grafting than grafting with methyl methacrylate/montmorillonite in all clay percentages, and also, the grafting yield of glycidyl methacrylate monomer onto cotton in the presence of montmorillonite clay had a higher value than that in the absence of the clay for all factors studied. Cotton grafted with glycidyl methacrylate montmorillonite with a graft yield of about 50% was prepared according to the emulsion polymerization technique and was treated with different concentrations of dibutylamine Solutions ranging from 1 to 4%. The obtained samples were characterized according to nitrogen content, thermal stability, scanning electron microscopy, mechanical properties, water absorption, and color strength according to acid, basic, and reactive dyes. (C) 2009 Wiley Periodicals, Inc. Appl Polym Sci 113: 492-501, 2009