Surface modification to fabricate dual superlyophobic mesh for efficient oil/water separation

被引:10
|
作者
Xu, Chang-Lian [1 ,2 ]
机构
[1] Sichuan Agr Univ, Coll Environm Sci, Chengdu 611130, Peoples R China
[2] Sichuan Univ, Collaborat Innovat Ctr Ecofriendly & Fire Safety, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, State Key Lab Polymer Mat Engn,Coll Chem, Chengdu 610064, Peoples R China
基金
中国国家自然科学基金;
关键词
Superlyophobic; Hydrothermal; Oil/water separation; Surface wettability; COATED MESH; WATER; REMOVAL; SYSTEMS;
D O I
10.1016/j.jclepro.2020.122872
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
How to solve water pollution caused by oil spills using special wetting materials with high efficiency is still a challenge. Herein, dual superlyophobic stainless steel mesh with hierarchical structures was produced via in-situ surface modification. Field emission scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy elemental (EDX) mapping results show that the frames of the mesh were fully covered by a layer of multi-scale structures. The mesh is both hydrophilic and oleophilic in air, whereas is dual superlyophobic in several kinds of oil-water systems due to its special structures. Artificial polluted waters were prepared using organic oils with diverse density, and then purified via the mesh with separation efficiency >99.90% even after 80 cycles. Moreover, the mesh has stable water penetration ability at various temperature with water flux of similar to to 53.8 L m(-2).s(-1). Water pollutions caused by viscous diesel oil or crude oil were well separated at 65 degrees C with high efficiency (>99.90%), and could also keep this high efficiency at 85 degrees C. Thus, not only a surface modification method is improved to fabricate dual superlyophobic materials, but also a superlyophobic mesh is produced to resolve oil pollution resulted from oil spills. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数:7
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