The Development of C-C Cross-Coupling Reaction of Monocarba-closo-dodecaborate Anion for the Synthesis of Functional Molecules

被引：1

作者：

Kanazawa, Junichiro ^{[1
]}

Takita, Ryo ^{[1
,2
]}

Uchiyama, Masanobu ^{[1
,2
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

[2] RIKEN, Elements Chem Lab, Wako, Saitama 3510198, Japan

来源：

YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN | 2014年 / 134卷 / 07期

关键词：

cross-coupling reaction; carborane anion; ionic liquid crystal; CHEMISTRY;

D O I：

10.1248/yakushi.14-00017-1

中图分类号：

R9 [药学];

学科分类号：

1007 ;

摘要：

A cross-coupling reaction at the carbon vertex of a monocarba-closo-dodecaborate has been developed to allow introduction of various aryl groups and other sp(2)/sp-hybridized carbon centers. A copper (I) complex facilitated the coupling process with a wide range of electrophiles at room temperature. The reaction was successfully used to prepare a series of C-arylated caborane anion derivatives, some of which showed potent androgen-receptor binding activity and excellent mesogenic properties.

引用

页码：783 / 788

页数：6

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