Double-chain structure of (pipzH2)[MnF2(HPO4)(H2O)](H2PO4)

被引：6
|
作者：
Stief, R
Massa, W [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
[2] Univ Marburg, Wissensch Zentrum Mat Wissensch, D-35032 Marburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 10期
关键词：
manganese; fluorophosphatomanganate(III); phosphate fluoride; crystal structure; Jahn-Teller effect; chain structure; hydrogen bonds;
D O I：
10.1002/zaac.200400157
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By adding piperazine to a hydrofluoric and phosphoric acid solution of Manganese(III) fluoride, the fluoride phosphate (pipzH(2))[MnF2(HPO4)(H2O)](H2PO4) can be crystallized. Its structure is built by piperazinium(2+) cations, (H2PO4)(-) anions, and an anionic double-chain of [HPO4] tetrahedra and [MnO3F2(H2O)] octahedra. The structure is triclinic, space group P (1) over bar, Z = 2, a = 622.97(4), b = 923.46(6), c = 1183.62(7) pm, alpha = 98.343(6)degrees, beta = 100.747(7)degrees, gamma = 107.642(5)degrees, R = 0.0289. It is worth noting that a ferrodistortive Jahn-Teller order is observed with [MnO3F2(H2O)] octahedra strongly elongated along the F-Mn-OH2 axes perpendicular to the chain plane. The structure is stabilized by very strong hydrogen bonds.
引用
收藏
页码：1459 / 1461
页数：3
相关论文
共 50 条
  • [1] Structure and 1D-magnetic properties of (pipzH2)[MnF4(H2PO4)]
    Stief, R
    Massa, W
    Pebler, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (12): : 2631 - 2636
  • [2] Synthesis, structure, and properties of [Re2(HPO4)2(H2PO4)2(H2O)2] · 4H2O
    A. V. Shtemenko
    V. G. Stolyarenko
    K. V. Domasevich
    Russian Journal of Coordination Chemistry, 2007, 33 : 79 - 84
  • [3] Synthesis, structure, and properties of [Re2(HPO4)2(H2PO4)2(H2O)2] • 4H2O
    Shtemenko, A. V.
    Stolyarenko, V. G.
    Domasevich, K. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (02) : 79 - 84
  • [4] Fluoromanganate(III) anions with new tetrameric and chain structures in (pipzH2)3[Mn4F18(H2O)]•(H2O) and (pipzH2)4[Mn2F9]2[MnF4(H2O)2][MnF4(HF)2]
    Stief, R
    Massa, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (13-14): : 2502 - 2507
  • [5] MnBa2(HPO4)(2)(H2PO4)(2)
    Sun, Wei
    Sun, Li-Zhi
    Zhu, Teng-Teng
    Zhao, Biao-Chun
    Mi, Jin-Xiao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : I49 - +
  • [6] Preparation and crystal structure of sodium iron hydrogen phosphate, NaFe(HPO4)(H2PO4)2 • H2O
    Anissimova, N
    Ilyukhin, A
    Chudinova, N
    Glaum, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (09): : 1509 - 1513
  • [7] Refinement of CaBa2 (HPO4)2(H2PO4)2
    Ben Tahar, L
    Smiri, L
    Driss, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1757 - 1759
  • [8] AL(H2PO4)(HPO4)(H2O), AN ACID PHOSPHATE WITH 2-DIMENSIONAL AL-O-P LINKING
    KNIEP, R
    MOOTZ, D
    WILMS, A
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (09): : 1047 - 1048
  • [9] [Ga4(C10H9N2)2(PO4)(H0.5PO4)2(HPO4)2(H2PO4)2(H2O)2]•H2O:: a novel one-dimensional chain structure containing four different types of monophosphate
    Chen, CY
    Lo, FR
    Kao, HM
    Lii, KH
    CHEMICAL COMMUNICATIONS, 2000, (12) : 1061 - 1062
  • [10] Synthesis, structure, and magnetism of CN3H6•VO(H2O)(HPO4)(H2PO4)•H2O, a new guanidinium vanadium(IV) phosphate
    Bircsak, Z
    Hall, AK
    Harrison, WTA
    JOURNAL OF SOLID STATE CHEMISTRY, 1999, 142 (01) : 168 - 173
12345