Indium-Catalyzed C-S Cross-Coupling of Aryl Halides with Thiols

被引：189

作者：

Reddy, V. Prakash ^{[1
]}

Swapna, K. ^{[1
]}

Kumar, A. Vijay ^{[1
]}

Rao, K. Rama ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 08期

关键词：

PHOSPHINE OXIDE LIGAND; TRANSITION-METAL; BOND FORMATION; DIARYL SULFIDES; BORONIC ACIDS; IODIDES; THIOETHERS; EFFICIENT; MECHANISM; ARYLATION;

D O I：

10.1021/jo802731j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium-catalyzed C-S cross-coupling of aromatic and alkane thiols with aryl halides proceeds smoothly in the presence of In(OTf)(3) (10 mol %), TMEDA (20 mol %), and KOH as a base in DMSO at 135 degrees C. When this protocol was utilized, a variety of thiols could be cross-coupled with aryl halides to afford the corresponding aryl sulfides in good to excellent yields.

引用

页码：3189 / 3191

页数：3

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