catena-poly[[[(pyrazino[2,3-f][1,10]phenanthroline)zinc(II)]-μ-cyclohexane-1,4-dicarboxylato] dihydrate]

被引：4

作者：

Che, GB ^{[1
]}

机构：

[1] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806018599

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, {[Zn(C8H10O4)(C14H8N4)].2H(2)O}(n) or [Zn(1,4-chdc)(PyPhen)].2H(2)O, where 1,4-chdc is the 1,4-cyclo-hexa-nedicarboxyl-ate dianion and PyPhen is pyrazino[2,3-f][1,10]phenanthroline, the Zn-II atom is six-coordinated by one chelating PyPhen and two bidentate 1,4-chdc ligands, resulting in a distorted cis-ZnN2O4 octa-hedral geometry. The Zn-II centres are bridged by the 1,4-chdc ligands, forming an infinite one-dimensional helical chain. In addition, neighbouring chains inter-act through pi-pi inter-actions, generating a two-dimensional network.

引用

页码：M1378 / M1380

页数：3

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