Two new compounds of polyoxoanions, transition metal complexes and organic amines

被引：5
作者：
Shi, Shu-Yun [1 ]
Chen, Ling-Yu [1 ]
Zhu, Tong-Hui [1 ]
Zhang, Jun [2 ]
Cui, Xiao-Bing [3 ,4 ]
机构：
[1] Jilin Normal Univ, Coll Environm Engn, Siping 136000, Peoples R China
[2] Anhui Jianzhu Univ, Sch Mat & Chem Engn, Hefei 230601, Anhui, Peoples R China
[3] Jilin Univ, Dept Chem, Coll Chem, Changchun 130023, Jilin, Peoples R China
[4] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Dept Chem, Changchun 130023, Jilin, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2018年 / 477卷
基金：
中国国家自然科学基金;
关键词：
Hydrothermally synthesized; Hydrogen bond; Supermolecular structure; Photodegradation; INORGANIC HYBRID COMPOUNDS; POLYOXOMETALATE CLUSTERS; HYDROTHERMAL SYNTHESES; BUILDING-BLOCKS; COORDINATION POLYMER; KEGGIN POLYOXOANIONS; CRYSTAL-STRUCTURES; LIGAND COMPLEXES; COPPER-COMPLEXES; FRAMEWORKS;
D O I：
10.1016/j.ica.2018.03.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two compounds [cu(biim)](2)(TEA)(2)[HPW12O40]center dot H2O (1); [Cu(im)(2)](im)[H2PMo12O40] (2), (biim = 2,2'-biimidazole, im = imidazole, TEA = triethylamine) have been hydrothermally synthesized and characterized by IR, XPS, XRD, UV-Vis, fluorescent spectra analysis, elemental analysis, X-ray diffraction analysis, cyclic voltammetric measurement and single crystal X-ray diffraction analysis. Single crystal X-ray diffraction analysis reveals that compounds 1-2 represent new examples formed by polyoxoanions, transition metal coordination complexes (TMCs) and organic amines. Compound 1 exhibits a 3-D super-molecular structure of which layers A and C are stacked alternatively, while compound 2 first shows a 1-D chain structure with an -A up arrow-A down arrow-A up arrow-A down arrow linking mode, then along a, b and c axis, respectively exhibits different beautiful 2-D supramolecular networks via hydrogen bond interactions.The photodegradation properties of compounds 1-2 have been investigated. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：292 / 299
页数：8
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