Spiro-annulated hole-transport material outperforms NPB with higher mobility and stability in organic light-emitting diodes

被引：22
作者：
Chen, Hua [1 ]
Gao, Chun-Hong [2 ]
Jiang, Zuo-Quan [2 ]
Zhang, Lei [2 ]
Cui, Lin-Song [2 ]
Ji, Shun-Jun [1 ]
Liao, Liang-Sheng [2 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[2] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Peoples R China
来源：
DYES AND PIGMENTS | 2014年 / 107卷
基金：
中国国家自然科学基金;
关键词：
Spiro-annulated structure; Electro-phosphorescence; Hole-transport material; Crystallization; Organic light-emitting diode; Triphenylamine; DEVICES; LAYER;
D O I：
10.1016/j.dyepig.2014.03.006
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel multifunctional spiro-annulated fluorene/triarylamine based compound (STNPB) has been designed, synthesized and characterized. It exhibits a high glass transition temperature of 140 degrees C, due to the rigid spiro-configuration molecular structure. According to its suitable energy level and triplet energy (2.34 eV), improved performances, such as lower driving voltage, enhanced device power efficiency, and longer stability, are shown in organic light-emitting diodes with STNPB as the hole-transport material, compared with the ones with the widely used arylamine derivative N,N'-bis(naphthalen-l-y1)-N,N'-bis(phenyl)-benzidine (NPB). Through further studies, it has been demonstrated that the enhanced stability is attributed to suppressed crystallization process as a result of employing STNPB instead of NPB as the hole-transport material. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：15 / 20
页数：6
相关论文
共 28 条
[1]   Synthesis and characterization of spiro(adamantane-2,9′-fluorene)-based triaryldiamines:: thermally stable hole-transporting materials [J].
Chen, CH ;
Shen, WJ ;
Jakka, K ;
Shu, CF .
SYNTHETIC METALS, 2004, 143 (02) :215-220
[2]   Synthesis of an aromatic amine derivative with novel double spirobifluorene core and its application as a hole transport material [J].
Cho, Yong Joo ;
Kim, Oh Young ;
Lee, Jun Yeob .
ORGANIC ELECTRONICS, 2012, 13 (03) :351-355
[3]   Effect of hole mobility through emissive layer on temporal stability of blue organic light-emitting diodes [J].
Culligan, Sean W. ;
Chen, Andrew C. -A. ;
Wallace, Jason U. ;
Klubek, Kevin P. ;
Tang, Ching W. ;
Chen, Shaw H. .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (11) :1481-1487
[4]   Enhanced Hole Injection in Phosphorescent Organic Light-Emitting Diodes by Thermally Evaporating a Thin Indium Trichloride Layer [J].
Gao, Chun-Hong ;
Cai, Shi-Duan ;
Gu, Wei ;
Zhou, Dong-Ying ;
Wang, Zhao-Kui ;
Liao, Liang-Sheng .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (10) :5211-5216
[5]   A hole-transporting material with controllable morphology containing binaphthyl and triphenylamine chromophores [J].
He, Qingguo ;
Lin, Hongzhen ;
Weng, Yufeng ;
Zhang, Bin ;
Wang, Zheming ;
Lei, Gangtie ;
Wang, Liduo ;
Qiu, Yong ;
Bai, Fenglian .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (10) :1343-1348
[6]   Chlorinated Indium Tin Oxide Electrodes with High Work Function for Organic Device Compatibility [J].
Helander, M. G. ;
Wang, Z. B. ;
Qiu, J. ;
Greiner, M. T. ;
Puzzo, D. P. ;
Liu, Z. W. ;
Lu, Z. H. .
SCIENCE, 2011, 332 (6032) :944-947
[7]   The development of anthracene derivatives for organic light-emitting diodes [J].
Huang, Jinhai ;
Su, Jian-Hua ;
Tian, He .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (22) :10977-10989
[8]   Bipolar anthracene derivatives containing hole- and electron-transporting moieties for highly efficient blue electroluminescence devices [J].
Huang, Jinhai ;
Su, Jian-Hua ;
Li, Xin ;
Lam, Mei-Ki ;
Fung, Ka-Man ;
Fan, Hai-Hua ;
Cheah, Kok-Wai ;
Chen, Chin H. ;
Tian, He .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (09) :2957-2964
[9]   Multifunctional Fluorene-Based Oligomers with Novel Spiro-Annulated Triarylamine: Efficient, Stable Deep-Blue Electroluminescence, Good Hole Injection, and Transporting Materials with Very High Tg [J].
Jiang, Zuoquan ;
Liu, Zhongyin ;
Yang, Chuluo ;
Zhong, Cheng ;
Qin, Jingui ;
Yu, Gui ;
Liu, Yunqi .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (24) :3987-3995
[10]   Red phosphorescent organic light-emitting diodes with indium tin oxide/single organic layer/Al simple device structure [J].
Joo, Chul Woong ;
Jeon, Soon Ok ;
Yook, Kyoung Soo ;
Lee, Jun Yeob .
ORGANIC ELECTRONICS, 2010, 11 (01) :36-40
123