Impact of gamma-ray irradiation on hardened white Portland cement pastes exposed to atmosphere

被引:50
作者
Maruyama, Ippei [1 ]
Ishikawa, Shunsuke [2 ,3 ]
Yasukouchi, Junichi [3 ]
Sawada, Shohei [3 ]
Kurihara, Ryo [2 ]
Takizawa, Masayuki [4 ]
Kontani, Osamu [3 ]
机构
[1] Nagoya Univ, Grad Sch Environm Studies, Chikusa Ku, ES Bldg,546 Furo Cho, Nagoya, Aichi 4648603, Japan
[2] Nagoya Univ, Grad Sch Environm Studies, Nagoya, Aichi, Japan
[3] Kajima Corp, Nucl Power Dept, Tokyo, Japan
[4] Mitsubishi Res Inst Inc, Nucl Safety Div, Tokyo, Japan
关键词
Gamma-ray irradiation; Carbonation (C); Calcium-silicate-hydrate (C-S-H) (B); Physical properties (C); C-S-H; SURFACE-AREA; WATER-VAPOR; ALUMINUM INCORPORATION; CALCIUM-CARBONATE; DRYING SHRINKAGE; COLLOID MODEL; CONCRETE; STRENGTH; AL-27;
D O I
10.1016/j.cemconres.2018.03.005
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Samples of matured hardened cement paste were exposed to an environment with gamma-ray irradiation, which induces a natural carbonation process. After a dose of approximately 5 x 10(4) kGy, the physical properties, microstructure, and phase composition of the irradiated hardened cement paste samples are compared with those of reference samples exposed to an identical environment without gamma-ray irradiation. Experiments confirm that aragonite and vaterite are preferentially formed under irradiation and that the bending strength is dramatically increased after gamma-ray irradiation. Based on field-emission scanning electron microscopy observations, X-ray scattering profiles, and water vapor sorption isotherm data, it is concluded that vaterite formed on C-S-H plays a role in strengthening the structure of C-S-H via pseudomorphs.
引用
收藏
页码:59 / 71
页数:13
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