Chiral Organosulfur Ligands/Catalysts with a Stereogenic Sulfur Atom: Applications in Asymmetric Synthesis

被引：346

作者：

Otocka, Sylwia ^{[1
,2
]}

Kwiatkowska, Malgorzata ^{[1
]}

Madalinska, Lidia ^{[1
]}

Kielbasinski, Piotr ^{[1
]}

机构：

[1] Polish Acad Sci, Dept Heteroorgan Chem, Ctr Mol & Macromol Studies, Sienkiewicza 112, PL-90363 Lodz, Poland

[2] Med Univ Lodz, Dept Biol Struct, Zeligowskiego 7-9, PL-90752 Lodz, Poland

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 05期

关键词：

N-SULFINYL UREA; DIELS-ALDER REACTIONS; CATALYZED ENANTIOSELECTIVE ADDITION; NON-BIARYL ATROPISOMERS; BIS-SULFOXIDE LIGAND; AZA-HENRY REACTION; ARYLBORONIC ACIDS; OLEFIN LIGANDS; ALLYL TRICHLOROSILANE; EFFICIENT LIGANDS;

D O I：

10.1021/acs.chemrev.6b00517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric synthesis, in which chiral organocatalysts or metal complexes with chiral ligands are used, has become the most valuable methodology for the preparation of enantiomerically pure organic compounds. Among such catalysts/ligands, a growing number constitute various organosulfur compounds. This Review provides comprehensive and critical information on the plethora of sulfur-based chiral ligands and organocatalysts used in asymmetric synthesis, which have been published within the last 15 years. However, it is confined to the presentation of only those chiral catalysts/ligands that possess a stereogenic sulfur atom and includes sulfoxides, sulfinamides, N-sulfinyl ureas, sulfoximines, and some related S-chiral derivatives.

引用

页码：4147 / 4181

页数：35

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