Amplification of light emission of chiral pyridine Eu(III) complex by copper nanoparticles

被引:13
作者
Reisfeld, Renata [1 ]
Levchenko, Viktoria [1 ]
Piccinelli, Fabio [2 ,3 ]
Bettinelli, Marco [2 ,3 ]
机构
[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel
[2] Univ Verona, DB, Lab Mat Luminescenti, I-37134 Verona, Italy
[3] INSTM, I-37134 Verona, Italy
关键词
Lanthanides; Fluorescence; Nanoparticles; Copper; ENHANCED FLUORESCENCE; METAL NANOPARTICLES; GOLD NANOPARTICLES; RHODAMINE-B; LUMINESCENCE; FILMS; GLASSES; EUROPIUM; IONS; DYES;
D O I
10.1016/j.jlumin.2015.09.023
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We outline the applications of lanthanides luminescence in a number of modern fields. The intensity of the luminescence of the expensive lanthanides can be increased by their interaction with nanoparticles of inexpensive copper. As a typical example the chiral pyridine-based Eu3+ complex was incorporated into amorphous films of polyvinyl alcohol with hydroxyethyl cellulose. The luminescence intensity of the complex is increased by three hundred percent by its interaction with copper nanoparticles. The synthesis and steady state spectroscopy of the materials are presented. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:820 / 824
页数:5
相关论文
共 41 条
[1]  
[Anonymous], PHILOS T R SOC LONDO, DOI DOI 10.1098/RSTL.1857.0011
[2]   Design of luminescent lanthanide complexes: From molecules to highly efficient photo-emitting materials [J].
Armelao, L. ;
Quici, S. ;
Barigelletti, F. ;
Accorsi, G. ;
Bottaro, G. ;
Cavazzini, M. ;
Tondello, E. .
COORDINATION CHEMISTRY REVIEWS, 2010, 254 (5-6) :487-505
[3]   Upconversion and anti-stokes processes with f and d ions in solids [J].
Auzel, F .
CHEMICAL REVIEWS, 2004, 104 (01) :139-173
[4]   Surface plasmon subwavelength optics [J].
Barnes, WL ;
Dereux, A ;
Ebbesen, TW .
NATURE, 2003, 424 (6950) :824-830
[5]   Enhanced fluorescence from Eu3+ in low-loss silica glass-ceramic waveguides with high SnO2 content [J].
Bhaktha, S. N. B. ;
Beclin, F. ;
Bouazaoui, M. ;
Capoen, B. ;
Chiasera, A. ;
Ferrari, M. ;
Kinowski, C. ;
Righini, G. C. ;
Robbe, O. ;
Turrell, S. .
APPLIED PHYSICS LETTERS, 2008, 93 (21)
[6]   Lanthanide-Based Luminescent Hybrid Materials [J].
Binnemans, Koen .
CHEMICAL REVIEWS, 2009, 109 (09) :4283-4374
[7]  
Bunzli J.C.G., 2014, Handbook on the Physics and Chemistry of Rare Earths, P169, DOI DOI 10.1016/B978-0-444-62711-7.00261-9
[8]  
Bunzli J-CG, 2014, HDB PHYS CHEM LANTHA
[9]   Taking advantage of luminescent lanthanide ions [J].
Bünzli, JCG ;
Piguet, C .
CHEMICAL SOCIETY REVIEWS, 2005, 34 (12) :1048-1077
[10]   Enhanced Photoluminescence at λ=1.54 μm in the Cu-Doped Er:SiO2 System [J].
Cattaruzza, Elti ;
Battaglin, Giancarlo ;
Visentin, Francesca ;
Trave, Enrico ;
Aquilanti, Giuliana ;
Mariotto, Gino .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (39) :21001-21011